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內容簡介

《Metal-Promoted Organic Reactions》重點介紹金屬促進的有機化學反應，全書由八部分組成，內容包括過渡金屬催化的通過SP2C-H官能化合成雜環(huán)化合物、過渡金屬催化的通過SP3C-H官能化合成雜環(huán)化合物、銅催化的芳烴C-H官能化、芳烴C-H轉化為C-N鍵、唑類化合物的胺化、雜環(huán)化合物不對稱官能化、烯烴醛酮和酰胺氫硅化、茂鈦族絡合物的合成及催化烯烴氫化等，對反應機理進行了詳細介紹。反映了相關領域的現(xiàn)狀并進行了展望。
　　《Metal-Promoted Organic Reactions》可供從事有機化學、藥物化學的科研人員參考，也可作為高等院校高年級本科生及研究生的教學參考書。

作者簡介

章明，江西師范大學化學化工學院，副教授，章明，男，副教授，江西師范大學化學化工學院教師，1992年從華東師范大學研究生畢業(yè)后，一直從事有機化學的教學與科研工作，2005年獲得副教授資格。一直從事與有機化學相關的科研工作，包括從天然藥物中分離有效成分、合成偶氮化合物并研究它們與金屬的顯色反應、合成抗生素和醫(yī)藥中間體、合成茂金屬配位化合物并利用它們催化氫化烯烴、有機合成方法學等。2003年后我開始關注有機合成方法學，在這方面做了一些科研，利用飽和碳-氫鍵活化合成了一系列異吲哚酮，這個工作發(fā)表在Heterocycles上，Ming Zhang,* Tianbao Chen, and Qinhua Liu，ISOINDOLONE SYNTHESIS VIA INTRAMOLECULAR COUPLING OF BENZYLIC C-H BONDS WITH AMIDE N-H BONDS. HETEROCYCLES 2014, 89,1255. 論文發(fā)表后立即受到國際同行的好評，Prof. Victor Snieckus from Queen’ s University, Canada 挑選該篇論文為 Highlights in Current Synthetic Organic Chemistry (當代合成有機化學的亮點)，見: Synfacts 2014, 10(6), 0571. 受邀為Advanced Synthesis ＆ Catalysis，Organometallics，Journal of Organometallic Chemistry，Current Organic Chemistry, Tetrahedron Letters，Synthetic Communications等雜志審稿。目前發(fā)表SCI收錄的論文22篇以上。
在國外專業(yè)期刊發(fā)表多篇關于有機合成方法學的綜述，其中在Advanced Synthesis & Catalysis（ADVANCED SYNTHESIS & CATALYSIS ，2009,351,2243-2270）發(fā)表的論文被引用83次。

目前正在主持的國家自然科學基金項目一項（No. 21262017 ）。

圖書目錄

1 Heterocycle Synthesis through Direct Coupling of Aromatic and Vinylic C-H Bonds
1.1 Introduction
1.2 Construction of carbazoles
1.2.1 Tandem C H functionalization and C N bond formation
1.2.2 Pd （OAc）2 catalyzed oxidative biaryl synthesis
1.3 Construction of benzoxazoles
1.4 Construction of benzimidazoles
1.5 Construction of 2 substituted benzothiazoles
1.6 Construction of 3 aryl/alkylindazoles
1.7 Construction of indoles
1.8 Construction of indole derivatives oxindoles and indolines
1.8.1 Construction of oxindoles
1.8.2 Construction of indolines
1.9 Construction of benzolactams and phthalimides
1.10 Construction of dibenzofurans
1.11 Construction of brigehead unsaturated bicyclic enamines
1.12 Conclusion
References

2 Heterocycle Synthesis through Direct Coupling of Saturated C-H Bonds
2.1 Introduction
2.2 Intramolecular cyclization
2.2.1 C C bond formation
2.2.2 C N bond formation
2.2.3 C O bond formation
2.3 Intermolecular cyclization
2.3.1 Cyclization with insertion of alkenes
2.3.2 Cyclization with insertion of CO
2.3.3 Cyclization with insertion of alkynes
2.4 Conclusions
References

3 Direct Coupling of Aromatic C-H Bonds with a Nitrogen Atom
3.1 Introduction
3.2 C N bond formation of arenes having directing groups
3.2.1 Copper catalyzed/mediated C N bond formation
3.2.2 Palladium catalyzed C N bond formation
3.3 Copper（Ⅱ） acetate catalyzed/mediated C N bond formation of polyfluoro（chloro）arenes
3.4 Metal free C N bond formation of alkyl substituted arenes
3.5 Conclusion

References
4 Direct Coupling of Azole C-H Bonds with Nitrogen Groups
4.1 Introduction
4.2 Copper catalyzed/mediated amination
4.3 Acid promoted amination
4.4 Metal free amination
4.5 Conclusion
References

5 Copper-Promoted Direct sp2C-H Bond Transformation
5.1 Introduction
5.2 Aromatic ring C H bond functionalization
5.2.1 Cyclization C H bond functionalization
5.2.2 Non cyclization C H bond functionalization
5.3 Heteroaromatic C H bond functionalization
5.3.1 Arylation of heteroaromatic C H bonds
5.3.2 Alkenylation of oxazoles with bromoalkenes
5.3.3 Amination of heteroaromatic C H bonds
5.4 Conclusion
References

6 lron Catalysis for Hydrosilyaltion
6.1 Introduction
6.2 Hydrosilylation of olefins
6.3 Hydrosilylation of aldehydes and ketones
6.4 Hydrosilylation reduction of amides to amines
6.5 Conclusion
References

7 Stereoselective Formation Chiral Heterocyclic Compounds via Cross Dehydrogenative Coupling Reactions of sp3C-H Bonds
7.1 Introduction
7.2 Copper catalyzed synthesis of tetrahydroisoquinoline derivatives
7.3 Organocatalytic synthesis of xanthene and indole derivatives
7.4 Copper catalyzed synthesis of indole derivatives
7.5 Conclusion
References

8 Synthesis of Cyclpentadienyl Titanium or Zirconium Complexes and Application in Hydrogenation of Olefins
8.1 Synthesis of cyclopentadienyl zirconium complexes
8.2 Synthesis of cyclopentadienyl titanium complexes
8.3 Hydrogenation of olefins using titanocenes
References